Adjustable structure transition and improved gases (H2, CO2) adsorption property of metal–organic framework MIL-53 by encapsulation of BNHx
2012; Royal Society of Chemistry; Volume: 41; Issue: 11 Linguagem: Inglês
10.1039/c2dt12463g
ISSN1477-9234
AutoresXiaoliang Si, Jian Zhang, Fen Li, Chengli Jiao, Shuang Wang, Shuang Liu, Zhibao Li, Huaiying Zhou, Lixian Sun, Fen Xu,
Tópico(s)Boron and Carbon Nanomaterials Research
ResumoThe structure transition of flexible MOF (MIL-53) can be adjusted by confinement of BNHx into MIL-53 channels. Hydrogen and carbon dioxide adsorption properties are also improved by incorporating BNHx. At 77 K and 1 atm pressure hydrogen storage capacity can reach 2.0 wt% and CO2 adsorption capacity is 4.5 mmol g−1 at 273 K 1 atm.
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