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Synthesis and structural characterisation of [Pd 2 (µ-Br) 2 (PBu t 3 ) 2 ], an example of a palladium( I )–palladium( I ) dimer

1996; Royal Society of Chemistry; Issue: 23 Linguagem: Inglês

10.1039/dt9960004313

2050-5671

Ramón Vilar, D. Michael P. Mingos, Christine J. Cardin,

Asymmetric Hydrogenation and Catalysis

The syntheses, spectroscopic characterisation and in one case (X = Br) the single-crystal structure of the novel PdI–PdI dimers [Pd2(µ-X)2(PBut3)2](X = Br or I) have been determined; preliminary results on their reactions with CO, H2, CNC6H3Me2 and C2H2 have also been obtained.