Synthesis of new soluble polybenzyls by Friedel-Crafts reactions
1999; Wiley; Volume: 48; Issue: 3 Linguagem: Inglês
10.1002/(sici)1097-0126(199903)48
ISSN1097-0126
AutoresFabrice Dumont, Fabienne Duriau-Montagne, Denise Baudry, A. Dormond,
Tópico(s)Inorganic and Organometallic Chemistry
ResumoSoluble polybenzyls were prepared by a catalytic electrophilic Friedel–Crafts type polycondensation between α,α′-dichloro-p-xylene and substituted (by an alkyl or an alkoxy side-chain) mesitylene. The influence of the length of the side-chain on the solubility of the polymer was examined. The polymers were found to be soluble in common organic solvents. Polymer characterizations were made by 13C nuclear magnetic resonance spectroscopy (NMR), size exclusion chromatography (SEC), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and elemental analysis. © 1999 Society of Chemical Industry
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