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Zirconium Phosphate Chloride Dimethyl Sulfoxide, a Reactive Precursor of a Large Family of Layered Compounds

1997; American Chemical Society; Volume: 36; Issue: 17 Linguagem: Inglês

10.1021/ic9704389

1520-510X

Giulio Alberti, Massimiliano Bartocci, Mauro Santarelli, Riccardo Vivani,

Inorganic Chemistry and Materials

A new layered compound of composition Zr(PO4)Cl(CH3)2SO has been prepared by the substitution of bidentate anionic groups O2P(OH)2- of γ-Zr(PO4)O2P(OH)2·2H2O with couples of monodentate Cl-−dimethyl sulfoxide ligands. The high reactivity of the new compound makes it a suitable precursor for the preparation of new layered derivatives of general formula Zr(PO4)LL', even containing functional groups of catalytic and electrochemical interest.