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Reversible Transformation of Two Diphenylphosphanido Ligands into the Neutral Tetraphenyldiphosphane Ligand

2005; Wiley; Volume: 44; Issue: 16 Linguagem: Inglês

10.1002/anie.200462498

1521-3773

J. Forniés, Consuelo Fortuño, Susana Ibáñez, Antonio Martı́n, Athanasios C. Tsipis, Constantinos A. Tsipis,

N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Angewandte Chemie International EditionVolume 44, Issue 16 p. 2407-2410 Communication Reversible Transformation of Two Diphenylphosphanido Ligands into the Neutral Tetraphenyldiphosphane Ligand† Juan Forniés Prof., Juan Forniés Prof. [email protected] Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187Search for more papers by this authorConsuelo Fortuño Dr., Consuelo Fortuño Dr. Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187Search for more papers by this authorSusana Ibáñez, Susana Ibáñez Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187Search for more papers by this authorAntonio Martín Dr., Antonio Martín Dr. Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187Search for more papers by this authorAthanasios C. Tsipis Dr., Athanasios C. Tsipis Dr. Section of Inorganic and Analytical Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, GreeceSearch for more papers by this authorConstantinos A. Tsipis Prof., Constantinos A. Tsipis Prof. [email protected] Laboratory of Applied Quantum Chemistry, Faculty of Chemistry, Aristotle University of Thessaloniki, 54006 Thessaloniki, Greece, Fax: (+30) 2310-99-7851Search for more papers by this author Juan Forniés Prof., Juan Forniés Prof. [email protected] Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187Search for more papers by this authorConsuelo Fortuño Dr., Consuelo Fortuño Dr. Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187Search for more papers by this authorSusana Ibáñez, Susana Ibáñez Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187Search for more papers by this authorAntonio Martín Dr., Antonio Martín Dr. Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187Search for more papers by this authorAthanasios C. Tsipis Dr., Athanasios C. Tsipis Dr. Section of Inorganic and Analytical Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, GreeceSearch for more papers by this authorConstantinos A. Tsipis Prof., Constantinos A. Tsipis Prof. [email protected] Laboratory of Applied Quantum Chemistry, Faculty of Chemistry, Aristotle University of Thessaloniki, 54006 Thessaloniki, Greece, Fax: (+30) 2310-99-7851Search for more papers by this author First published: 13 April 2005 https://doi.org/10.1002/anie.200462498Citations: 37 † Polynuclear Homo- or Heterometallic Palladium(II)-Platinum(II) Pentafluorophenyl Complexes Containing Bridging Diphenylphosphido Ligands, Part 16. Part 15: I. Ara, N. Chaouche, J. Forniés, C. Fortuño, A. Kribii, A. C. Tsipis, C. A. Tsipis, Inorg. Chim. Acta DOI: 10.1016/j.ica.2004.04.006. This work was supported by the Ministerio de Ciencia y Tecnología y Fondos FEDER (Project BQU2002-03997-C02-02) and the Diputación General de Aragón. S.I. thanks the Ministerio de Ciencia y Tecnología for a grant. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract From a theoretical prediction to an experimental finding: Oxidation of two bridging diphenylphosphanido ligands to a neutral tetraphenyldiphosphane is predicted theoretically and achieved experimentally in a trinuclear Pt2Pd complex (see scheme, RF=C6F5, P*=PPh2). Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z462498_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume44, Issue16April 15, 2005Pages 2407-2410 RelatedInformation