Synthesis of C‐18 mixed acid diacyl‐ sn ‐glycerol enantiomers
1971; Wiley; Volume: 6; Issue: 10 Linguagem: Inglês
10.1007/bf02531299
ISSN1558-9307
Autores Tópico(s)Food Chemistry and Fat Analysis
ResumoAbstract Procedures have been developed for the synthesis of both enantiomeric forms of mixed fatty acid, saturated and polyunsaturated 1,2‐diacyl‐ sn ‐glycerols and 2,3‐diacyl‐ sn ‐glycerols from D‐mannitol as starting material. The following diacyl‐ sn ‐glycerols have been synthesized: 1‐Stearoyl‐2‐linoleoyl‐ sn ‐glycerol, 1‐stearoyl‐2‐linolenoyl‐ sn ‐glycerol, 2‐linoleoyl‐3‐stearoyl‐ sn ‐glycerol and 2‐linolenoyl‐3‐oleoyl‐ sn ‐glycerol. Their specific rotations, refractive indices, densities, solubilities, carbon and hydrogen analysis and iodine values have been reported.
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