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Artigo Revisado por pares
BIBTEX RIS

Cobalt-Catalyzed Hydroazidation of Olefins: Convenient Access to Alkyl Azides

2005; American Chemical Society; Volume: 127; Issue: 23 Linguagem: Inglês

10.1021/ja052164r

ISSN

1943-2984

Autores

Jérôme Waser, Hisanori Nambu, Erick M. Carreira,

Tópico(s)

Chemical Synthesis and Analysis

Resumo

Conversion of olefins to azides was achieved with high Markovnikov selectivity for a broad range of alkenes using 6 mol % Co(BF4).6H2O and ligand 1, with 3 equiv of TsN3 as nitrogen source and simple silanes (PhSiH3, TMDSO).

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