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Novel synthesis of syn-α,β-epoxy alcohols by diastereoselective carbonyl reduction of α,β-epoxy ketones

1994; Elsevier BV; Volume: 35; Issue: 46 Linguagem: Inglês

10.1016/s0040-4039(00)78454-1

1873-3581

Takayo Kawakami, Ikuya Shibata, Akio Baba, Haruo Matsuda, Noboru Sonoda,

Asymmetric Synthesis and Catalysis

Abstract A novel tin hydride reagent, Bu 3 SnH-Bu 4 NCN, reduced α,β-epoxy ketones to the corresponding syn -α,β-epoxy alcohols in high diastereoselectivities.