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Inner-Phase Stabilization of Reactive Intermediates

2001; Wiley; Volume: 2001; Issue: 3 Linguagem: Inglês

10.1002/1099-0690(200102)2001

1434-193X

Ralf Warmuth,

Chemical Reaction Mechanisms

European Journal of Organic ChemistryVolume 2001, Issue 3 p. 423-437 Microreview Inner-Phase Stabilization of Reactive Intermediates Ralf Warmuth, Ralf Warmuth warmuth@ksu.edu Department of Chemistry, Kansas State University, Manhattan, Kansas 66506-3701, U.S.A., Fax: (internat.) + 1-785/532-6666Search for more papers by this author Ralf Warmuth, Ralf Warmuth warmuth@ksu.edu Department of Chemistry, Kansas State University, Manhattan, Kansas 66506-3701, U.S.A., Fax: (internat.) + 1-785/532-6666Search for more papers by this author First published: 08 January 2001 https://doi.org/10.1002/1099-0690(200102)2001:3 3.0.CO;2-2Citations: 77Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract Molecular container compounds are spherical, hollow molecules with inner cavities (inner phases) that are large enough to accommodate a single guest molecule. These inner phases are superb environments for the stabilization and spectroscopic investigation of important reactive intermediates. The surrounding host protects the incarcerated reactive intermediate from dimerization or from a reaction with bulk-phase reactants that are too large to enter the inner phase by passing through a portal in the host shell. Citing Literature Volume2001, Issue3February 2001Pages 423-437 RelatedInformation