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Adsorption of amine and paints on H‐form resin from electrodeposition waste water

1990; Wiley; Volume: 36; Issue: 12 Linguagem: Inglês

10.1002/aic.690361205

1547-5905

Hiroyuki Yoshida, Kazuyuki Shimizu, Takeshi Kataoka,

Electrochemical Analysis and Applications

Abstract Wastewater of electrodeposition painting process contained diisopropanolamine, unknown three paints, and solvents (butylcellosolve and/or ethylcellosolve). The recovery of the amine and paints from the real wastewater by adsorption on an H‐form strong acid ion exchanger appeared feasible technically and economically. Equilibrium isotherms and breakthrough curves have been determined experimentally. The selectivity for the amine adsorption on the resin was fairly high. Solvents were not adsorbed on the resin. The components of the wastewater showed typical breakthrough curves for multicomponent system. Theoretical breakthrough curves and intraparticle effective diffusivities of the amine were determined from the analytic solution for rectangular isotherm in the single‐component system. Experiments of adsorption, elution and regeneration also have been repeated. The amine and paints adsorbed on the resin were eluted completely by NaOH aqueous solution. The adsorption capacity of the amine did not change with repeat times, and the intraparticle effective diffusivity of the amine was constant after the second cycle.