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Artigo Revisado por pares
BIBTEX RIS

KINETICS OF OXIDATION OF AQUEOUS SODIUM SULPHIDE SOLUTIONS BY GASEOUS OXYGEN IN A STIRRED CELL REACTOR

1985; Taylor & Francis; Volume: 36; Issue: 1-6 Linguagem: Inglês

10.1080/00986448508911264

ISSN

1563-5201

Autores

E. Alper, Şaile Tuba Öztürk,

Tópico(s)

Industrial Gas Emission Control

Resumo

Abstract The oxidation of aqueous sodium sulphide solutions (0.13-1.00 kmol/m3) by pure oxygen at atmospheric pressure was studied in a stirred cell with an unbroken interface. The temperature ranged between 278-308 K and the pH was maintained at 13 by using 0.6 kmol/m3 sodium hydroxide. Gas absorption rate measurements were analysed using Danckwerts' plots in order to obtain reaction kinetics data. Results showed that the reaction rate followed first order kinetics with respect to both oxygen and sulphide concentrations and had an activation energy of 14.07 kcal/mol. KEYWORDS: Gas-liquid reactionsulphide oxidationDanckwerts' plot. stirred cell. Additional informationNotes on contributorsE. ALPER Author to whom correspondence should be addressed

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