Sharpless epoxidation by in situ generation of furylhydroperoxides
1992; Elsevier BV; Volume: 33; Issue: 37 Linguagem: Inglês
10.1016/s0040-4039(00)79114-3
ISSN1873-3581
AutoresRoberto Antonioletti, Francesco Bonadies, Alessandra Lattanzi, Edith Monteagudo, Arrigo Scettri,
Tópico(s)Organic Chemistry Cycloaddition Reactions
ResumoThe compatibility of the generation of furylhydroperoxides by a radical chain process with the presence of oxygen acceptors and transition metal catalysts allows the achievement of a modified Sharpless procedure for the epoxidation of allylic alcohols and oxidation of sulphides to sulphoxides.
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