Understanding the M(NHC) (NHC=N-heterocyclic carbene) bond
2008; Elsevier BV; Volume: 253; Issue: 5-6 Linguagem: Inglês
10.1016/j.ccr.2008.06.006
ISSN1873-3840
AutoresHeiko Jacobsen, Andrea Correa, Albert Poater, Chiara Costabile, Luigi Cavallo,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoN-heterocyclic carbenes (NHC) is a well established class of new ligands in organometallic chemistry. Their use as ligands in many reactions catalyzed by transition metal complexes has stimulated intensive research to understand the unique features of the M(NHC) bond. This review is aimed to provide an overview of the main contributions achieved by the application of advanced computational techniques.
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