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Soft and Hard Molecule-Based Magnets of Formula [(Etrad)2M2{Cu(opba)}3]⋅S [Etrad+=Radical Cation, MII=MnII or CoII, opba=Ortho-phenylenebis(oxamato), S=Solvent Molecules], with a Fully Interlocked Structure

1999; Wiley; Volume: 5; Issue: 5 Linguagem: Inglês

10.1002/(sici)1521-3765(19990503)5

1521-3765

Maria G. F. Vaz, L.M.M. Pinheiro, Humberto O. Stumpf, Antônio F. C. Alcântara, Stéphane Golhen, Lahcène Ouahab, Olivier Cador, Corine Mathonière, Olivier Kahn,

Porphyrin and Phthalocyanine Chemistry

Chemistry – A European JournalVolume 5, Issue 5 p. 1486-1495 Full Paper Soft and Hard Molecule-Based Magnets of Formula [(Etrad)2M2{Cu(opba)}3]⋅S [Etrad+=Radical Cation, MII=MnII or CoII, opba=Ortho-phenylenebis(oxamato), S=Solvent Molecules], with a Fully Interlocked Structure Maria G. F. Vaz, Maria G. F. Vaz Departamento de Química, ICEx Universidade Federal de Minas Gerais, Belo Horizonte, MG 31.270–901(Brazil), Fax: (+55) 314995700Search for more papers by this authorLuiza M. M. Pinheiro, Luiza M. M. Pinheiro Departamento de Química, ICEx Universidade Federal de Minas Gerais, Belo Horizonte, MG 31.270–901(Brazil), Fax: (+55) 314995700Search for more papers by this authorH. O. Stumpf, H. O. Stumpf [email protected] Departamento de Química, ICEx Universidade Federal de Minas Gerais, Belo Horizonte, MG 31.270–901(Brazil), Fax: (+55) 314995700Search for more papers by this authorAntônio F. C. Alcântara, Antônio F. C. Alcântara Departamento de Química, ICE Fundação Universidade do Amazonas, Manaus, AM 69.078–000(Brazil)Search for more papers by this authorStéphane Golhen, Stéphane Golhen Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS No 6511, Université de Rennes 1, 35042 Rennes (France)Search for more papers by this authorLahcène Ouahab, Lahcène Ouahab Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS No 6511, Université de Rennes 1, 35042 Rennes (France)Search for more papers by this authorOlivier Cador, Olivier Cador Laboratoire des Sciences Moléculaires, Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS No 9048, 33608 Pessac (France), Fax: (+33) 56–84–26–49Search for more papers by this authorCorine Mathonière, Corine Mathonière Laboratoire des Sciences Moléculaires, Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS No 9048, 33608 Pessac (France), Fax: (+33) 56–84–26–49Search for more papers by this authorOlivier Kahn, Olivier Kahn [email protected] Laboratoire des Sciences Moléculaires, Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS No 9048, 33608 Pessac (France), Fax: (+33) 56–84–26–49Search for more papers by this author Maria G. F. Vaz, Maria G. F. Vaz Departamento de Química, ICEx Universidade Federal de Minas Gerais, Belo Horizonte, MG 31.270–901(Brazil), Fax: (+55) 314995700Search for more papers by this authorLuiza M. M. Pinheiro, Luiza M. M. Pinheiro Departamento de Química, ICEx Universidade Federal de Minas Gerais, Belo Horizonte, MG 31.270–901(Brazil), Fax: (+55) 314995700Search for more papers by this authorH. O. Stumpf, H. O. Stumpf [email protected] Departamento de Química, ICEx Universidade Federal de Minas Gerais, Belo Horizonte, MG 31.270–901(Brazil), Fax: (+55) 314995700Search for more papers by this authorAntônio F. C. Alcântara, Antônio F. C. Alcântara Departamento de Química, ICE Fundação Universidade do Amazonas, Manaus, AM 69.078–000(Brazil)Search for more papers by this authorStéphane Golhen, Stéphane Golhen Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS No 6511, Université de Rennes 1, 35042 Rennes (France)Search for more papers by this authorLahcène Ouahab, Lahcène Ouahab Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS No 6511, Université de Rennes 1, 35042 Rennes (France)Search for more papers by this authorOlivier Cador, Olivier Cador Laboratoire des Sciences Moléculaires, Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS No 9048, 33608 Pessac (France), Fax: (+33) 56–84–26–49Search for more papers by this authorCorine Mathonière, Corine Mathonière Laboratoire des Sciences Moléculaires, Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS No 9048, 33608 Pessac (France), Fax: (+33) 56–84–26–49Search for more papers by this authorOlivier Kahn, Olivier Kahn [email protected] Laboratoire des Sciences Moléculaires, Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS No 9048, 33608 Pessac (France), Fax: (+33) 56–84–26–49Search for more papers by this author First published: 23 April 1999 https://doi.org/10.1002/(SICI)1521-3765(19990503)5:5 3.0.CO;2-FCitations: 128AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract The fine-tuning of the critical temperature and the coercivity of compounds with two interpenetrating quasi-perpendicular honeycomblike networks (see diagram) are presented. Molecule-based magnets of formula [(Etrad)2M2{Cu(opba)}3]⋅S and mixed compounds of formula [Etrad2Mn2−2xCo2xCu3] were synthesized and their magnetic properties were investigated. References 1 J. S. Miller, J. C. Calabrese, A. J. Epstein, R. W. Bigelow, J. H. Zang, W. M. Reiff, J. Chem. Soc. Chem. Commun. 1986, 1026. Google Scholar 2 J. S. Miller, J. C. Calabrese, H. Rommelman, S. R. Chittipedi, J. H. Zang, W. M. Reiff, A. J. Epstein, J. Am. Chem. Soc. 1987, 109, 769. 10.1021/ja00237a023 CASWeb of Science®Google Scholar 3 Y. Pei, M. Verdaguer, O. Kahn, J. Sletten, J.-P. Renard, J. Am. Chem. Soc. 1986, 108, 428. Google Scholar 4 O. Kahn, Y. Pei, M. Verdaguer, J.-P. Renard, J. Sletten, J. Am. Chem. Soc. 1988, 110, 782. 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