Preparation and catalytically study of metal–organic frameworks of amine/MIL-53 (Al) as a powerful option in the rapid N-formylation condensation in neat conditions
2015; Elsevier BV; Volume: 428; Linguagem: Inglês
10.1016/j.ica.2015.01.031
ISSN1873-3255
AutoresSadegh Rostamnia, Ziba Karimi,
Tópico(s)Chemical Synthesis and Reactions
ResumoThis paper reports on the preparation and application of amine/MIL-53 (Al) as highly active catalysts for the N-formylation reaction. These Al-MOFs were found to be an efficient, selective and waste-free green solid catalyst for the net condensation of amines and formic acid. The catalyst can be isolated from the reaction mixture and reused at least 6 times.
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