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Characterisation of microcellular foams produced from semi-crystalline PCL using supercritical carbon dioxide

2006; Elsevier BV; Volume: 42; Issue: 11 Linguagem: Inglês

10.1016/j.eurpolymj.2006.07.022

1873-1945

Michael J. Jenkins, Kate Harrison, M.M.C.G. Silva, Martin J. Whitaker, Kevin M. Shakesheff, Steven M. Howdle,

Phase Equilibria and Thermodynamics

Microcellular foams were produced from polycaprolactone (PCL) using a method based on the rapid release of supercritical CO2. The average pore size in the structure was found to vary with the selected vent time and the final microstructure was a combination of open and closed cells. Thermal analysis showed that the degree of crystallinity of all foams was in the region of 70%. This was found to be consistent with the observation of lamellar textures on the inner surface of the pores. There was also a pronounced decrease in compressive modulus with increasing vent time and average pore size.