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Paramagnetic Transition Metal Complexes With [sgrave]-Bonded Tetracyanoethylene (TCNE)

1995; Volume: 273; Issue: 1 Linguagem: Inglês

10.1080/10587259508031837

1058-725X

Kim R. Dunbar, Xiang Ouyang,

Organometallic Complex Synthesis and Catalysis

Abstract Mono- and dimetallic building blocks are being studied in charge-transfer reactions with organic π-acceptors such as TCNE to form zero-, one-, and two-dimensional hybrid donor/acceptor compounds. In particular, tetracarboxylate-bridged dinuclear and solvated 3d mononuclear complexes with [sgrave]-bonded TCNE ligands are being investigated with regards to their variable temperature magnetic behavior. Results of experiments with dimolybdenum, diruthenium and vanadium complexes are discussed.