Tricyclic diterpenes from Halimium viscosum
1998; Elsevier BV; Volume: 47; Issue: 8 Linguagem: Inglês
10.1016/s0031-9422(97)00794-2
ISSN1873-3700
AutoresJesús M. Rodilla, Dina I. M. D. de Mendonça, Julio G. Urones, Rosalina F. Moro, David Williams,
Tópico(s)Natural product bioactivities and synthesis
ResumoSeveral tricyclic diterpenes with a valparane skeleton have been isolated from the aerial parts of Halimium viscosum collected at Celorico da Beira, Portugal. Two new compounds have been identified as valpara-2,15-diene-1,4-dione and 3α,4α-epoxyvalpar-15-en-2-one, besides the previously known compounds: valpara-2,13-diene; valpara-2,15-diene; valpara-3,15-dien-2-one; 2β,3β-epoxyvalpar-14-ene and 1β-metoxy-valpara-2,15-diene. Their structures have been established by means of 2D NMR experiments (1H13C, and HMQC) and X-ray studies. This plant sample may represent a new chemotype.
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