
Efeito da composição das correntes do conversor das unidades de FCC no desempenho catalítico de aditivos DESOx
2009; Brazilian Chemical Society; Volume: 32; Issue: 1 Linguagem: Inglês
10.1590/s0100-40422009000100007
ISSN1678-7064
AutoresCarla Maria Salerno Polato, Jose ́Luiz Fontes Monteiro, Cristiane A. Henriques,
Tópico(s)Layered Double Hydroxides Synthesis and Applications
ResumothE StREaMS tO thE FCC CONVERtER UNIt ON thE CatalytIC PERFORMaNCE OF DESOx aDDItIVES.hydrotalcite-like compounds having Mg partially replaced by Cu or Mn were prepared and used as precursors for two mixed oxides (Cu-OM50 and Mn-OM50) that were evaluated for SO x removal in the presence of O 2 , NO and CO.Under SO 2 /O 2 reaction system, SO x removal was slightly higher over Cu-OM50. the addition of CO and NO to the feed markedly hindered the SO 2 oxidation over Cu-OM50 while no significant effect was observed for Mn-OM50.For the regeneration step, the use of propane instead of h 2 reduces regeneration capacity, mainly for Cu-OM50.Mn-OM50 was less affected by the feed composition, suggesting that it was a promising additive for SO x removal.
Referência(s)