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Amphiphilic Self‐Assembly of an n‐Type Nanotube

2010; Wiley; Volume: 49; Issue: 42 Linguagem: Inglês

10.1002/anie.201003415

1521-3773

Hui Shao, James Seifert, Natalie C. Romano, Min Gao, Jonathan Helmus, Christopher P. Jaroniec, David A. Modarelli, Jon R. Parquette,

Polydiacetylene-based materials and applications

Mmm—stacks of donuts! A one-dimensional n-type nanotube was formed by stacking rings formed from the bolaamphiphilic self-assembly of 1,4,5,8-naphthalenetetracarboxylic acid diimide (NDI) with L-lysine headgroups (see picture). Solid-state NMR studies demonstrate the exceptional conformational homogeneity of the constituent molecules that make up the nanotubes. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.