The electron energy-loss and Auger spectra of Ir4(CO)12: Comparison with XPS shake-up and UV-absorption spectra
1980; Elsevier BV; Volume: 18; Issue: 2 Linguagem: Inglês
10.1016/0368-2048(80)80047-8
ISSN1873-2526
AutoresH. Netzer, E. Bertel, J.A.D. Matthew,
Tópico(s)Catalytic Processes in Materials Science
ResumoElectron energy-loss and Auger spectra of condensed Ir4 (CO)12 are presented in relation to corresponding phenomena for molecularly adsorbed CO and to XPS shake-up in transition-metal carbonyls. Distinctions between the properties of mono-metal-atom clusters and multi-metal-atom clusters are established, and possible differences in the electronic excitation of weakly and strongly adsorbed CO are discussed.
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