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Reduction factors for dynamic Jahn-Teller systems in strong coupling

1979; IOP Publishing; Volume: 12; Issue: 2 Linguagem: Inglês

10.1088/0022-3719/12/2/019

1747-3802

Mary Claire O’Brien, D R Pooler,

Advanced Chemical Physics Studies

The linear Jahn-Teller system E(X) epsilon , Gamma 8(X) tau 2 and Gamma 8(X)( epsilon (+) tau 2) (in equal coupling) can all be reduced to similar sets of differential equations. Wavefunctions, energies and Ham factors for low-lying levels of such systems in strong coupling are found. The agreement between the results of analytical and numerical calculations is good.