Theory of conductance and related isothermal transport coefficients in electrolytes
1983; American Institute of Physics; Volume: 78; Issue: 6 Linguagem: Inglês
10.1063/1.445093
ISSN1520-9032
AutoresAndrzej R. Altenberger, Harold L. Friedman,
Tópico(s)Advanced Thermodynamics and Statistical Mechanics
ResumoThe transport coefficients are calculated from consideration of the fluctuations in local ion concentrations in view of a recent advance in the theory of inhomogeneous systems at equilibrium. The theory is applicable to mixed electrolytes of arbitrary charge type and to frequency dependent phenomena, although the example worked out here is for the zero frequency coefficients for a binary electrolyte.
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