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Dielectric studies of nematic-smectic A-reentrant nematic transition in the 8OCB/6OCB mixtures

1989; Taylor & Francis; Volume: 4; Issue: 2 Linguagem: Inglês

10.1080/02678298908029068

1366-5855

Jan Jadżyn, G. Czechowski,

Photochemistry and Electron Transfer Studies

Abstract The results of measurement of the anisotropies of the electric permittivity and conductivity for pure 8OCB and 6OCB together with their mixtures are presented. It was found that (i) the dielectric properties of mesophases composed of molecules with a strong tendency to antiparallel association in the nematic phase (8OCB) and molecules which do not exhibit such a tendency (6OCB) undergo a drastic change in mixtures with a relatively low concentration of 6OCB, (ii) the effect of smectic density modulation in the N-SA-NR sequence is very subtle, and (iii) for concentrations higher than a critical value the nematic phase exhibits a smectic-like ordering which vanishes with increasing concentration of 6OCB.