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The first mixed-valence MnII,III gallium phosphate: synthesis and structural characterization of (C4H12N2)2Mn2Ga5(H2O)(PO4)8

2000; Royal Society of Chemistry; Issue: 2 Linguagem: Inglês

10.1039/a908334k

1364-548X

Kuei‐Fang Hsu, Sue‐Lein Wang,

Mesoporous Materials and Catalysis

The synthesis and characterization of a novel mixed-valence MnGaPO phase is described; the 3D open-framework consists of discrete bioctahedra of Ga2O10(H2O) and GaO5 trigonal bipyramids, connected via MnIIIO4, MnIIO4 and PO4 tetrahedra to generate intersecting tunnels within which piperazinium cations reside.