Liquid/liquid Electrochemistry in Electroanalysis: Fundamentals Revisited
2009; Institute of Physics; Volume: 19; Issue: 6 Linguagem: Inglês
10.1149/1.3118537
ISSN2151-2051
AutoresPetr Vanýsek, Vítězslav Novák,
Tópico(s)Advanced Chemical Sensor Technologies
ResumoThe interface between two polarized liquids has applications in electroanalytical chemistry as a practical transducer arrangement. With same importance, such interface is studied with great interest by theoretical chemist and physicists to garner information about the fine structure of such interface. In our work we touch both of these aspects. In order to correlate the x-ray experimental work we determined Gibbs energies of transport for one supporting electrolyte and present a systematic method for determination of such parameters.
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