Artigo Revisado por pares

Recycling of uPVC window profile waste

2005; Wiley; Volume: 11; Issue: 3 Linguagem: Inglês

10.1002/vnl.20047

ISSN

1548-0585

Autores

Adrian Kelly, R. M. Rose, R. Spares, Phil Coates, Sally Weston,

Tópico(s)

Extraction and Separation Processes

Resumo

Journal of Vinyl and Additive TechnologyVolume 11, Issue 3 p. 119-126 Research Article Recycling of uPVC window profile waste A.L. Kelly, Corresponding Author A.L. Kelly [email protected] IRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKIRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKSearch for more papers by this authorR.M. Rose, R.M. Rose IRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKSearch for more papers by this authorR. Spares, R. Spares IRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKSearch for more papers by this authorP.D. Coates, P.D. Coates IRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKSearch for more papers by this authorS. Weston, S. Weston Costdown Ltd., Warrington, UKSearch for more papers by this author A.L. Kelly, Corresponding Author A.L. Kelly [email protected] IRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKIRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKSearch for more papers by this authorR.M. Rose, R.M. Rose IRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKSearch for more papers by this authorR. Spares, R. Spares IRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKSearch for more papers by this authorP.D. Coates, P.D. Coates IRC in Polymer Engineering, School of Engineering Design and Technology, University of Bradford, Bradford BD7 1DP, UKSearch for more papers by this authorS. Weston, S. Weston Costdown Ltd., Warrington, UKSearch for more papers by this author First published: 10 August 2005 https://doi.org/10.1002/vnl.20047Citations: 10AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract Methods of recycling unplasticized polyvinyl chloride (uPVC) window frame waste were investigated. The quality of untreated granular waste was compared to that of waste treated by a range of contaminant removal processes including melt filtration and dissolution. Processability of each recyclate was evaluated by using a highly instrumented single screw extruder that enabled melt viscosity and process variation to be monitored in real time. Product quality measurements such as mechanical properties and surface defects were made on extruded strip, and the nature of the stabilizers present was determined. The mechanical properties of recyclates were found to be comparable to or better than those of virgin material in all cases and conformed to industry standards for window profile. Contaminant removal stages significantly reduced the amount of large surface defects detected in extrudate. Processability was comparable to that of virgin compounds, but melt viscosity varied among different batches of recyclate, depending on the source and composition of the original PVC formulation. J. VINYL ADDIT. TECHNOL., 11:119–126, 2005. © 2005 Society of Plastics Engineers REFERENCES 1 K.A. Brown, M.R. Holland, R.A. Boyd, S. Thresh, H. Jones, and S.M. Ogilvie, “ Economic Evaluation of PVC Waste Management,” Study for DG XI of the European Commission (2000). 2 E. Plinke, N. Wenk, G. Wolff, D. Castiglione, and M. Palmark, “ Mechanical Recycling of PVC Wastes,” Study for DG XI of the European Commission (2000). 3 I. Mersiowsky, Prog. Polym. Sci., 27, 2227 (2002). 4 E.B. Rabinovitch and P.C. Booth, J. Vinyl Addit. Technol., 12, 43 (1990). 5 H.-K. Boo, B.K. Mikofalvy, J.W. Summers, D.H. Mittendorf, and W.A. Sell, SPE ANTEC, 6, 1934 (1992). 6 M. Gneuss, Kunstst.-Ger. Plast., 93, 34 (2003). 7 G. Dodbiba, A. Shibayama, J. Sadaki, and T. Fujita, Mater. T. JIM., 44, 2427 (2003). 8 J.M. Yernaux and R. Saffert, Kunstst.-Ger. Plast., 91, 118 (2001). 9 R. Buhl, Polimery-W, 48, 63 (2003). 10 P.D. Coates, A.L. Kelly, R.M. Rose, S. Weston, and R. Morton, “ Materials and Products from UK-Sourced PVC-Rich Waste,” Waste and Resources Action Programme; Project PLA 7–013 (2004). 11 P.D. Coates, R.M. Rose, M. Woodhead, and A.L. Kelly, Int. Polym. Process., 13, 172 (1998). 12 F.N. Cogswell, Polymer Melt Rheology: A Guide for Industrial Practice, Godwin, London (1981). 13 “British Standard BS2782 Method 320C,” Methods of Testing Plastics. Part 3: Mechanical Properties (1976). 14 “British Standard EN ISO 179-1,” Plastics. Determination of Charpy Impact Properties. Non-instrumented Impact Test (2001). 15 A.L. Kelly, M. Woodhead, R.M. Rose, and P.D. Coates, Plast. Rubber Compos., 29, 23 (2000). 16 “British Standard BS7413:2002,” Unplasticized PVC Profiles for Windows and Doors (2002). 17 European Commission 1992 revision of EC/76/769 Cadmium Directive (1992). 18 A.S. Ditta, A.J. Wilkinson, G.M. McNally, and W.R. Murphy, SPE ANTEC, Paper No. 749 (2004). Citing Literature Volume11, Issue3September 2005Pages 119-126 ReferencesRelatedInformation

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