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BIBTEX RIS

Synthesis and Structure of the First Hybrid Borazine—Phosphazene Ring

1994; Wiley; Volume: 33; Issue: 22 Linguagem: Inglês

10.1002/anie.199422771

ISSN

1521-3773

Autores

Derek P. Gates, Ralf Ziembinski, Ian Manners, Arnold L. Rheingold, Brian S. Haggerty,

Tópico(s)

Flame retardant materials and properties

Resumo

One boron—chlorine bond perpendicular to the plane of the ring is significantly longer than the in-plane BCl bond—this is the surprising result of the X-ray structure analysis of the BNP heterocycle 1. The zwitterion 1 reacts with GaCl3 under halide abstraction to give 2, which possesses the first authentic hybrid borazine—phosphazene ring [Eq. (a)].

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