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Microwave Spectroscopy in the Region of Three to Five Millimeters

1949; American Institute of Physics; Volume: 75; Issue: 2 Linguagem: Inglês

10.1103/physrev.75.260

1536-6065

Alex Smith, Walter Gordy, James W. Simmons, William V. Smith,

Inorganic Fluorides and Related Compounds

Exploratory investigations in the region of the electromagnetic spectrum between 3.3- and 5-mm wave-length have shown that useful work can be done here with available sources and detectors. Higher rotational transitions of BrCN and ICN have been observed with satisfactory signal-to-noise ratios at pressures low enough to resolve the nuclear quadrupole splittings. These measurements indicate that the minimum detectable absorption is ${10}^{\ensuremath{-}5}$ neper per cm with the present spectroscope. The ${B}_{0}$ value of HCN has been determined as 1.4789 ${\mathrm{cm}}^{\ensuremath{-}1}$, in agreement with infra-red results. The quadrupole coupling factor for the nitrogen nucleus in this molecule has been found to be 4.7 mc.