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BIBTEX RIS

Photoinduced Elimination of H2 from [Mo(η5-C5H5)2H2]. Generation of Molybdenocene.

1977; Elsevier BV; Volume: 134; Issue: 2 Linguagem: Inglês

10.1016/s0022-328x(00)81427-8

ISSN

1872-8561

Autores

Gregory L. Geoffroy, Mark Bradley,

Tópico(s)

Metalloenzymes and iron-sulfur proteins

Resumo

Ultraviolet irradiation of deaerated solutions of [Mo(η5-C5H5)2H2] results in elimination of H2 and generation of [Mo(η5-C5H5)2]. The transient molybdenocene can be trapped with substrates such as CO, C2H2, and PR3 to yield stable adducts, but in the absence of substrate, oligomerization to the previously described [Mo(η5-C5H5)2]x occurs.

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