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ε‐Caprolactamium Hydrogen Sulfate: An Ionic Liquid Used for Decades in the Large‐Scale Production of ε‐Caprolactam

2008; Wiley; Volume: 1; Issue: 3 Linguagem: Inglês

10.1002/cssc.200700135

1864-564X

Viktória Fábos, Diána Lantos, Andrea Bodor, Ana‐Maria Bálint, László T. Mika, Ot E. Sielcken, Agnes Cuiper, István T. Horváth,

Analytical Chemistry and Chromatography

ChemSusChemVolume 1, Issue 3 p. 189-192 Communication ε-Caprolactamium Hydrogen Sulfate: An Ionic Liquid Used for Decades in the Large-Scale Production of ε-Caprolactam Viktória Fábos, Viktória Fábos Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorDiána Lantos, Diána Lantos Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorAndrea Bodor, Andrea Bodor Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorAna-Maria Bálint, Ana-Maria Bálint Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorLászló T. Mika, László T. Mika Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorOt E. Sielcken, Ot E. Sielcken DSM Research, P.O. Box 18, 6160 MD Geleen, The NetherlandsSearch for more papers by this authorAgnes Cuiper, Agnes Cuiper DSM Research, P.O. Box 18, 6160 MD Geleen, The NetherlandsSearch for more papers by this authorIstván T. Horváth Prof., István T. Horváth Prof. istvan.t.horvath@att.net Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, Hungary, Fax: (+36) 1-372-2617Search for more papers by this author Viktória Fábos, Viktória Fábos Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorDiána Lantos, Diána Lantos Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorAndrea Bodor, Andrea Bodor Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorAna-Maria Bálint, Ana-Maria Bálint Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorLászló T. Mika, László T. Mika Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, HungarySearch for more papers by this authorOt E. Sielcken, Ot E. Sielcken DSM Research, P.O. Box 18, 6160 MD Geleen, The NetherlandsSearch for more papers by this authorAgnes Cuiper, Agnes Cuiper DSM Research, P.O. Box 18, 6160 MD Geleen, The NetherlandsSearch for more papers by this authorIstván T. Horváth Prof., István T. Horváth Prof. istvan.t.horvath@att.net Institute of Chemistry, Eötvös University, Pázmány Péter sétány 1/A H-1117 Budapest, Hungary, Fax: (+36) 1-372-2617Search for more papers by this author First published: 17 March 2008 https://doi.org/10.1002/cssc.200700135Citations: 25Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract An iconic liquid: Investigation of the mechanism of the Beckmann rearrangement of cyclohexanone oxime to ε-caprolactam (1) in sulfuric acid or oleum has led to the conclusion that the manufacturing process for ε-caprolactam is in fact the largest-scale industrial technology that has been using an ionic liquid, caprolactamium hydrogen sulfate (2), as the reaction medium for decades. Citing Literature Volume1, Issue3March 25, 2008Pages 189-192 RelatedInformation