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Progress toward the Total Synthesis of Ciguatoxins: A Convergent Synthesis of the FGHIJKLM Ring Fragment

2002; American Chemical Society; Volume: 4; Issue: 16 Linguagem: Inglês

10.1021/ol026306n

1523-7060

Hiroyuki Takakura, Makoto Sasaki, Shugo Honda, Kazuo Tachibana,

Oxidative Organic Chemistry Reactions

[structure: see text] A highly convergent synthetic route to the FGHIJKLM ring fragment of ciguatoxins has been developed, which relied on extensive use of the B-alkyl Suzuki-Miyaura coupling reaction.