Blue LED light-sensitive benzo pyrazolo (or imidazo) isoquinolinone derivatives in high-performance photoinitiating systems for polymerization reactions
2014; Wiley; Volume: 53; Issue: 4 Linguagem: Inglês
10.1002/pola.27477
ISSN1099-0518
AutoresPu Xiao, Frédéric Dumur, Bernadette Graff, Jing Zhang, Fabrice Morlet‐Savary, Didier Gigmès, Jean Pierre Fouassier, Jacques Lalevée,
Tópico(s)Photochromic and Fluorescence Chemistry
ResumoJournal of Polymer Science Part A: Polymer ChemistryVolume 53, Issue 4 p. 567-575 Article Blue LED light-sensitive benzo pyrazolo (or imidazo) isoquinolinone derivatives in high-performance photoinitiating systems for polymerization reactions Pu Xiao, Pu Xiao Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceSearch for more papers by this authorFrédéric Dumur, Frédéric Dumur Aix-Marseille Université, CNRS, ICR, UMR 7273, F-13397 Marseille, FranceSearch for more papers by this authorBernadette Graff, Bernadette Graff Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceSearch for more papers by this authorJing Zhang, Jing Zhang Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceSearch for more papers by this authorFabrice Morlet-Savary, Fabrice Morlet-Savary Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceSearch for more papers by this authorDidier Gigmes, Didier Gigmes Aix-Marseille Université, CNRS, ICR, UMR 7273, F-13397 Marseille, FranceSearch for more papers by this authorJean Pierre Fouassier, Jean Pierre Fouassier Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, France ENSCMu-UHA, 3 rue Alfred Werner, 68093 Mulhouse Cedex, FranceSearch for more papers by this authorJacques Lalevée, Corresponding Author Jacques Lalevée Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceCorrespondence to: J. Lalevée (E-mail: [email protected])Search for more papers by this author Pu Xiao, Pu Xiao Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceSearch for more papers by this authorFrédéric Dumur, Frédéric Dumur Aix-Marseille Université, CNRS, ICR, UMR 7273, F-13397 Marseille, FranceSearch for more papers by this authorBernadette Graff, Bernadette Graff Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceSearch for more papers by this authorJing Zhang, Jing Zhang Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceSearch for more papers by this authorFabrice Morlet-Savary, Fabrice Morlet-Savary Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceSearch for more papers by this authorDidier Gigmes, Didier Gigmes Aix-Marseille Université, CNRS, ICR, UMR 7273, F-13397 Marseille, FranceSearch for more papers by this authorJean Pierre Fouassier, Jean Pierre Fouassier Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, France ENSCMu-UHA, 3 rue Alfred Werner, 68093 Mulhouse Cedex, FranceSearch for more papers by this authorJacques Lalevée, Corresponding Author Jacques Lalevée Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, FranceCorrespondence to: J. Lalevée (E-mail: [email protected])Search for more papers by this author First published: 10 December 2014 https://doi.org/10.1002/pola.27477Citations: 16 Conflict of interest: The authors declare no competing financial interest. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL ABSTRACT Isoquinolinone derivatives (IQ) have been synthesized and combined with different additives (an amine, 2,4,6-tris(trichloromethyl)-1,3,5-triazine, an iodonium salt, or N-vinylcarbazole) to produce reactive species (i.e. radicals and cations) being able to initiate the radical polymerization of acrylates, the cationic polymerization of epoxides, the thiol-ene polymerization of trifunctional thiol/divinylether, and the synthesis of epoxide/acrylate interpenetrated polymer network IPN upon exposure to very soft polychromatic visible lights, blue laser diode or blue LED lights. Compared with the use of camphorquinone based systems, the novel combinations employed here ensures higher monomer conversions (∼50–60% vs. ∼15–35%) and better polymerization rates in radical polymerization. The chemical mechanisms are studied by steady-state photolysis, fluorescence, cyclic voltammetry, laser flash photolysis, and electron spin resonance spin trapping techniques. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 567–575 Citing Literature Supporting Information Additional Supporting Information may be found in the online version of this article. Filename Description pola27477-sup-0001-suppinfo.doc203 KB Supporting Information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume53, Issue415 February 2015Pages 567-575 RelatedInformation
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