Penning ionization electron spectroscopy of CO and Fe(CO)5. Study of electronic structure of Fe(CO)5 from electron distribution of individual molecular orbitals
1983; American Institute of Physics; Volume: 79; Issue: 7 Linguagem: Inglês
10.1063/1.446218
ISSN1520-9032
AutoresYoshihisa Harada, Koichi Ohno, Hideki Mutoh,
Tópico(s)Catalytic Processes in Materials Science
ResumoThe He* Penning ionization electron spectra (PIES) and He I UV photoelectron spectra (UPS) of CO and Fe(CO)5 were measured. The relative intensity of the bands in PIES was shown to give information on the spatial electron distribution of individual molecular orbitals. On the basis of the information together with the results of the population analysis, most of the bands in the UPS of Fe(CO)5 were assigned. The usefulness of PIES in the study of stereochemistry was indicated.
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