Facile intermolecular aromatic C–F bond activation reaction of [Ru(dmpe) 2 H 2 ](dmpe = Me 2 PCH 2 CH 2 PMe 2 )
1996; Royal Society of Chemistry; Issue: 6 Linguagem: Inglês
10.1039/cc9960000787
ISSN1364-548X
AutoresMichael K. Whittlesey, Robin N. Perutz, M. H. Moore,
Tópico(s)Catalytic C–H Functionalization Methods
Resumocis-[Ru(dmpe)2H2] reacts at –78 °C with hexafluorobenzene to generate the pentafluorophenyl hydride complex,trans-[Ru(dmpe)2(C6F5)H]; reaction also takes place with C6F5H, C6F5CF3, C6F5OCH3,1,2,3,4-C6F4H2 and 1,2,3-C6F3H3 to yield products from C–F insertion exclusively.
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