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Yb(fod)3-promoted ene reaction of aldehydes with vinyl ethers

1993; Elsevier BV; Volume: 34; Issue: 15 Linguagem: Inglês

10.1016/s0040-4039(00)60428-8

1873-3581

Melissa V. Deaton, Marco A. Ciufolini,

Analytical Chemistry and Chromatography

Catalytic amounts of Yb(fod)3 catalyze a bimolecular ene-like reaction between ordinary aldehydes and vinyl ethers, in which the oxygen functionality is located at the central carbon of an allylic system. These reactions proceed at room temperature in high yield.