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Direct Electron Transfer Between Ligninolytic Redox Enzymes and Electrodes

2004; Wiley; Volume: 16; Issue: 13-14 Linguagem: Inglês

10.1002/elan.200403004

1521-4109

Andreas Christenson, Nina Dimcheva, Elena E. Ferapontova, Lo Gorton, Tautgirdas Ruzgas, Leonard Stoica, Sergey Shleev, A. I. Yaropolov, Dietmar Haltrich, R. N. F. Thorneley, Steven D. Aust,

Electrochemical Analysis and Applications

Abstract The electrochemistry of the ligninolytic redox enzymes, which include lignin peroxidase, manganese peroxidase and laccase and possibly also cellobiose dehydrogenase, is reviewed and discussed in conjunction with their basic biochemical characteristics. It is shown that long‐range electron transfer between these enzymes and electrodes can be established and their ability to degrade lignin through a direct electron transfer mechanism is discussed.