Herstellung von Vinyl-iodiden durch Umsetzung von Vinyl-triflaten mit Magnesiumiodid
1986; Thieme Medical Publishers (Germany); Volume: 1986; Issue: 03 Linguagem: Inglês
10.1055/s-1986-31624
ISSN1437-210X
AutoresAntonio García Martínez, Roberto Martínez Álvarez, Amelia Garcı́a Fraile, L. R. Subramanian, Michael Hanack,
Tópico(s)Coordination Chemistry and Organometallics
ResumoSynthesis of Vinyl Iodides from Vinyl Triflates and Magnesium Iodide The reaction of vinyl trifluoromethanesulfonates (triflates) with anhydrous magnesium iodide in the presence of triethylamine in carbon disulfide or cyclohexane gives vinyl iodides in good yields. No reaction is observed with phenyl and cyclopentenyl triflate under these conditions.
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