Synthesis and characterisation of 3,4-dialkoxy-substituted benzo-1,3,2-dithiazolyl radicals
2010; Royal Society of Chemistry; Volume: 46; Issue: 33 Linguagem: Inglês
10.1039/c0cc01282c
ISSN1364-548X
AutoresAntonio Alberola, D.J. Eisler, Robert J. Less, Efrén Navarro‐Moratalla, Jeremy M. Rawson,
Tópico(s)Perovskite Materials and Applications
ResumoThe conversion of 3,4-dialkoxy-benzenes into dialkoxy-benzo-1,3,2-dithiazolyls is described and representative examples (1 and 2) derived from benzodioxole and veratrol, respectively, are reported. Whilst 1 is a dimeric pi*-pi* dimer, the dimethoxy derivative 2 is monomeric in the solid state and exhibits antiferromagnetic interactions.
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