Partially fluorinated enamines and their electrochemical fluorination
1993; Elsevier BV; Volume: 63; Issue: 3 Linguagem: Inglês
10.1016/s0022-1139(00)80563-1
ISSN1873-3328
AutoresD.D. Moldavsky, G. I. Kaurova, T. A. Bispen, G. G. Furin,
Tópico(s)Fluorine in Organic Chemistry
ResumoThe reactions of hexafluoropropylene, its dimers and trimers, and perfluoro-1-ethylcyclo- hex-1-ene with secondary amines (dipropylamine, dibutylamine and diallylamine) have been shown to form enamines. The enamines were electrochemically fluorinated in anhydrous hydrogen fluoride. This paper reports the electrochemical fluorination data for the fluorination of tripropylamine, tributylamine, triamylamine and the partially fluorinated enamines. The structures of the products have been confirmed by 19F NMR and GC—MS methods.
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