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First X-ray determination of cyclopropane structure in methanofullerenes

1994; Royal Society of Chemistry; Issue: 13 Linguagem: Inglês

10.1039/c39940001607

2050-5639

Jens Osterodt, Martin Nieger, Fritz Vögtle,

Chemical Reactions and Mechanisms

The X-ray crystal structure of [(3,4-dimethoxyphenyl)phenylmethano][60]fullerene 1 confirming firstly the cyclopropane structure for methanofullerenes is reported; one of two chloroform molecules (enclosed in the crystal lattice) forms a hydrogen bond pattern to both oxygen atoms of 1.