Photoreductive decarboxylation of carboxylic acids via their benzophenone oxime esters
1987; Elsevier BV; Volume: 28; Issue: 49 Linguagem: Inglês
10.1016/s0040-4039(00)61848-8
ISSN1873-3581
AutoresMasato Hasebe, Takashi Tsuchiya,
Tópico(s)Oxidative Organic Chemistry Reactions
ResumoDecarboxylation of various carboxylic acids, including ∝β- andamino acids, is performed by the photolysis of their benzophenoneoxime esters in isopropanol in the presence of t-butyl mercaptane,and corresponding decarboxylated products are obtained in goodyields under mild photolytic conditions.
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