A Novel Dirhodium Compound with Neutral, Bridging 9-Ethyladenine Ligands
1997; American Chemical Society; Volume: 36; Issue: 11 Linguagem: Inglês
10.1021/ic960682k
ISSN1520-510X
AutoresK.V. Catalan, Daniel J. Mindiola, Donald L. Ward, Kim R. Dunbar,
Tópico(s)Magnetism in coordination complexes
ResumoThe new cationic complex cis-Rh2(μ-DTolF)2(CH3CN)6][BF4]2 (1) was prepared and reacted with the purine 9-ethyladenine to afford the novel compound cis-[Rh2(μ-DTolF)2(μ-9-EtAH)2(CH3CN)][BF4]2 (2) with two bridging 9-EtAH ligands. The solid-state and solution structures of 1 and 2 have been determined by X-ray crystallography and 1H NMR spectroscopy. Compound 2 represents the first reported dirhodium compound with bridging adenines rather than the expected axially coordinated form.
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