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Evidence for a radical cage mechanism in the thermal elimination of benzaldoxime thiocarbamates

1976; Royal Society of Chemistry; Issue: 14 Linguagem: Inglês

10.1039/c39760000539

2050-5639

R. F. Hudson, Keith A. F. Record,

Insect and Pesticide Research

The sodium salt of benzaldoxime and phenyl isothiocyanate give the corresponding O-[(p-tolyl)thiocarbamoyl]oxime which spontaneously eliminates benzonitrile at least partly by a radical-cage mechanism.