Mercury-chlorine exchange rates in chloride ion probe experiments
1974; Elsevier BV; Volume: 16; Issue: 2 Linguagem: Inglês
10.1016/0022-2364(74)90045-6
ISSN1557-8968
Autores Tópico(s)Analytical chemistry methods development
ResumoThe importance of chemical exchange in determining the 35Cl linewidth in chloride ion probe measurements of protein-bound mercury sites is assessed. It is shown that in some cases the exchange rate may determine the observed broadening of the chloride ion resonance and in other cases it does not, depending on the protein investigated.
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