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BIBTEX RIS

The synthesis of new paracyclophane complexes of ruthenium(II): Crystal structure of [Ru(η6-C16H16)Cl(C5H5N)2][PF6]

1988; Elsevier BV; Volume: 356; Issue: 1 Linguagem: Inglês

10.1016/0022-328x(88)80687-9

ISSN

1872-8561

Autores

M.R.J. Elsegood, Derek A. Tocher,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

The dimer [Ru(η6-C16H16)Cl2]2 reacts with ligands L (L  PMe2Ph, PPh3, C5H5N) to give both neutral monomeric [Ru(η6-C16H16)Cl2L] and cationic monomeric [Ru(η6-C16H16)ClL2]+ products. One example, [Ru(η6-C16H16)Cl(C5H5N)2]-[PF6], has been characterised by X-ray crystallography. Reaction with the bidentate ligand 2,2′-bipyridyl gives the mononuclear cation [Ru(η6-C16H16)Cl(bipy)]+, isolated as its [BPh4]− salt, whereas reaction with OMe− or OEt− gives dinuclear products [Ru(η6-C16H16)2(OR)3]+.

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