A comparison of the vibrational structures of ethanol, acetic acid, and acetaldehyde adsorbed on alumina
1979; American Institute of Physics; Volume: 71; Issue: 12 Linguagem: Inglês
10.1063/1.438317
ISSN1520-9032
AutoresHoward E. Evans, W. H. Weinberg,
Tópico(s)Spectroscopy and Quantum Chemical Studies
ResumoThe adsorption on aluminum oxide of acetaldehyde (CH3CHO) and acetic acid (CH3COOH) has been studied by utilizing inelastic electron tunneling spectroscopy (IETS) to probe the vibrational structures of the surface species over the spectral range between 240 and 4000 cm−1. Results for temperatures between 295 and 475 K are compared with our previous IETS results for ethanol (CH3CH2OH) adsorption on alumina up to 575 K. Although all three hydrocarbons form acetate complexes with the surface under certain conditions, slight differences in bonding and structure are evident in the IET spectra. The formation of some bulk aluminum hydroxide is observed also in certain cases. Observed variations in surface concentrations, bulk hydration, and the nature of surface hydroxyl groups are related to previous experimental results. Mechanisms are substantiated for the initial adsorption and subsequent reaction of each hydrocarbon with the surface.
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