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Solubilities of gases in liquids II. The solubilities of He, Ne, Ar, Kr, O2, N2, CO, CO2, CH4, CF4, and SF6 in n-octane 1-octanol, n-decane, and 1-decanol

1978; Elsevier BV; Volume: 10; Issue: 9 Linguagem: Inglês

10.1016/0021-9614(78)90154-4

1096-3626

Robert J. Wilcock, Rubin Battino, W. F. Danforth, Emmerich Wilhelm,

Chemical Thermodynamics and Molecular Structure

The solubilities of 11 gases in n-octane, n-decane, 1-octanol, and 1-decanol have been determined at atmospheric pressure in the range 293 to 313 K. From the temperature variation of the experimental solubilities, partial molar enthalpies and entropies of solution for 1 atm partial pressure of gas and 298.15 K have been derived. Comparison with results obtained through application of scaled-particle theory showed satisfactory agreement.