The absolute configuration of oudemansin total synthesis of (−)-oudemansin
1983; Elsevier BV; Volume: 24; Issue: 19 Linguagem: Inglês
10.1016/s0040-4039(00)81829-8
ISSN1873-3581
AutoresHiroyuki Akita, H. KOSHIJI, Akiya Furuichi, Koki Horikoshi, Takeshi Oishi,
Tópico(s)Chemical synthesis and alkaloids
Resumo(−)-Oudemansin (1) was synthesized from the optically active intermediate 10 obtained by microbiological asymmetric reduction of β-keto ester 3. Oudemansin was found to have the 9S, 10S absolute configuration.
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