C−H and C−C Bond Activation of Primary Amines through Dehydrogenation and Transimination
2001; American Chemical Society; Volume: 3; Issue: 5 Linguagem: Inglês
10.1021/ol015563+
ISSN1523-7060
AutoresChul‐Ho Jun, Kwan-Yong Chung, Jun-Bae Hong,
Tópico(s)Asymmetric Synthesis and Catalysis
Resumo[structure: see text]. Dehydrogenation and subsequent transimination of primary amines offer a new pathway for C-H bond activation, ortho-alkylation, and C-C bond activation to afford a variety of ketones in the reaction of 1-alkene by a cocatalyt system of Rh(I) and 2-amino-3-picoline.
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